The Phase Rule
The phase rule is a general principle governing systems in thermodynamic equilibrium. If F is the number of degrees of freedom, C is the number of components and P is the number of phases, then
{ F=C-P+2. F=C-P+2.}
It was derived by Josiah Willar...See more
d Gibbs in his landmark paper titled On the Equilibrium of Heterogeneous Substances, published in parts between 1875 and 1878. The rule assumes the components do not react with each other.
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